|论文题目||Preparation and photoluminescence of novel La8Ca2(Si4P2O22N2)O-2 oxynitride phosphors containing Eu2+/Ce3+/Tb3+ ions|
|作 者||; Langping Dong, Liang Zhang, Wei Lü, Baiqi Shao, Shuang Zhao and Hongpeng You*|
|发表年度||MAR 7 2019|
|卷、期、页码||48; 9; 3028-3037|
A series of novel Eu2+/Ce3+/Tb3+ ion doped La8Ca2(Si4P2O22N2)O-2-based apatite structure oxynitride phosphors have been synthesized by a solid-state method. The phase purity has been checked by X-ray diffraction (XRD) and the Rietveld method. The photoluminescence excitation (PLE) spectra indicate that the obtained phosphors have broad excitation bands in the n-UV range, which is a favourable property for application as n-UV-WLED phosphors. The concentration quenching has been investigated in detail. The temperature-dependent luminescence and efficiency study shows that the as-prepared phosphors have a good thermal stability and high quantum efficiency. Moreover, a warm white LED device with a low color temperature of 4288 K and a high color rendering index (R-a) of 80.8 has been obtained by coating a La8Ca1.99(Si4P2O22N2)O-2:0.01Eu(2+) phosphor with a (Sr,Ca)AlSiN3:Eu2+ red phosphor on a n-UV chip. Our results reveal that the La8Ca2(Si4P2O22N2)O-2:Eu2+ phosphor is a promising bluish-green phosphor for WLEDs.