|论文题目||Controllable Synthesis of Highly Uniform Nanosized HKUST-1 Crystals by LSS method|
|作 者||Xuechao Cai; Zhongxi Xie,Maolin Pang* and Jun Lin*|
|刊物名称||Crystal Growth & Design|
|卷、期、页码||; 2; 556-561|
Nowadays, preparation of nanosized metal-organic frameworks (NMOFs) has attracted great attention for diverse applications, such as drug delivery, biological imaging, catalysis, and functional membranes. In this report, highly uniform nanosized HKUST-1 crystals with sizes from about 30 to 140 nm were obtained by the liquid-solidsolution (LSS) method, which is mainly based on a general phase transfer and separation mechanism occurring at the interfaces of the liquid, solid, and solution phases. The SEM, TEM, PXRD, FTIR, TGA, and gas adsorption-desorption analysis results demonstrated the successful preparation of nanosized HKUST-1 crystals. This work further proves its feasibility of the LSS method to synthesize NMOFs, which may open up a facile and universal method to facilitate the fundamental research on preparing NMOFs.