论文题目 | Controllable Synthesis of Highly Uniform Nanosized HKUST-1 Crystals by LSS method |
作 者 | Xuechao Cai; Zhongxi Xie,Maolin Pang* and Jun Lin* |
发表年度 | 2019 |
刊物名称 | Crystal Growth & Design |
卷、期、页码 | ; 2; 556-561 |
影响因子 | |
论文摘要 | Nowadays, preparation of nanosized metal-organic frameworks (NMOFs) has attracted great attention for diverse applications, such as drug delivery, biological imaging, catalysis, and functional membranes. In this report, highly uniform nanosized HKUST-1 crystals with sizes from about 30 to 140 nm were obtained by the liquid-solidsolution (LSS) method, which is mainly based on a general phase transfer and separation mechanism occurring at the interfaces of the liquid, solid, and solution phases. The SEM, TEM, PXRD, FTIR, TGA, and gas adsorption-desorption analysis results demonstrated the successful preparation of nanosized HKUST-1 crystals. This work further proves its feasibility of the LSS method to synthesize NMOFs, which may open up a facile and universal method to facilitate the fundamental research on preparing NMOFs. |
全文链接 | DOI:?10.1021/acs.cgd.8b01695 |
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